Frontiers

Constraints on superoxide mediated formation of manganese oxides

Manganese (Mn) oxides are among the most reactive sorbents and oxidants within the environment, where they play a central role in the cycling of nutrients, metals, and carbon (Jenne, 1968; Sunda and ...
C&EN

Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes

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Europe PMC

A Common Active Intermediate in the Oxidation of Alkenes, Alcohols and Alkanes with H2O2 and a Mn(II)/Pyridin‐2‐Carboxylato Catalyst

Abstract The mechanism and the reactive species involved in the oxidation of alkenes, and alcohols with H2O2, catalysed by an in situ prepared mixture of a MnII salt, pyridine‐2‐carboxylic acid and a ...
Europe PMC

Hydrogen peroxide oxidation of o-vanillin fluorescence kinetic fluorescence method for the determination of Mn(II)Hydrogen peroxide oxidation of o-vanillin fluorescence kinetic ...

In this experiment, a newly synthesized chromogenic agent o-vanillin fluorescence ketone was used to establish a method for the determination of Mn(II) by catalytic kinetic fluorescence. At the ...
C&EN

Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes

† QBIS Research Group, Institut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona, Campus Montilivi, Girona E-17071, Catalonia, Spain ...